{
  "metadata": {
    "versie": "1.0",
    "datum": "2026-04-27",
    "locatie": "Phoenix Metals — Tata Steel terrein, IJmuiden",
    "opslagniveau": "C",
    "opslagniveau_wbdbo": 60,
    "bron": "Niveaubepaling v2.0 + Stoffenlijst Phoenix Metals",
    "status": "CONCEPT"
  },
  "stoffen": [
    {
      "id": 1,
      "naam": "Sodium hydroxide, 50% in water",
      "naam_nl": "Natriumhydroxide 50% oplossing",
      "cas": "1310-73-2",
      "adr_klasse": 8,
      "adr_verpakkingsgroep": "II",
      "adr_un": "UN 1824",
      "vorm": "vloeistof",
      "hoeveelheid_liter": 100,
      "hoeveelheid_kg": 120,
      "eenheid": "L",
      "verpakking": "Jerrycan",
      "clp_classificatie": ["Skin Corr. 1A"],
      "h_zinnen": ["H314"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 2",
      "pgs15_ondergrens_kg": 250,
      "boven_ondergrens": false,
      "adr_niveau": "basis",
      "clp_niveau": null,
      "opmerkingen": "Sterk basisch, corrosief. Individueel onder grens, bijdragend aan ADR 8 aggregaat."
    },
    {
      "id": 2,
      "naam": "Sulfuric acid, 75% in water",
      "naam_nl": "Zwavelzuur 75% oplossing",
      "cas": "7664-93-9",
      "adr_klasse": 8,
      "adr_verpakkingsgroep": "II",
      "adr_un": "UN 2796",
      "vorm": "vloeistof",
      "hoeveelheid_liter": 30,
      "hoeveelheid_kg": 50,
      "eenheid": "L",
      "verpakking": "Jerrycan",
      "clp_classificatie": ["Skin Corr. 1A"],
      "h_zinnen": ["H314"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 1",
      "pgs15_ondergrens_kg": 250,
      "boven_ondergrens": false,
      "adr_niveau": "basis",
      "clp_niveau": null,
      "opmerkingen": "Concentratie >15% → ADR 8 VG II."
    },
    {
      "id": 3,
      "naam": "Sulfuric acid, 50% in water",
      "naam_nl": "Zwavelzuur 50% oplossing",
      "cas": "7664-93-9",
      "adr_klasse": 8,
      "adr_verpakkingsgroep": "II",
      "adr_un": "UN 2796",
      "vorm": "vloeistof",
      "hoeveelheid_liter": 70,
      "hoeveelheid_kg": 110,
      "eenheid": "L",
      "verpakking": "Jerrycan",
      "clp_classificatie": ["Skin Corr. 1A"],
      "h_zinnen": ["H314"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 1",
      "pgs15_ondergrens_kg": 250,
      "boven_ondergrens": false,
      "adr_niveau": "basis",
      "clp_niveau": null,
      "opmerkingen": ""
    },
    {
      "id": 4,
      "naam": "Sulfuric acid, 25% in water",
      "naam_nl": "Zwavelzuur 25% oplossing",
      "cas": "7664-93-9",
      "adr_klasse": 8,
      "adr_verpakkingsgroep": "II",
      "adr_un": "UN 2796",
      "vorm": "vloeistof",
      "hoeveelheid_liter": 100,
      "hoeveelheid_kg": 120,
      "eenheid": "L",
      "verpakking": "Jerrycan",
      "clp_classificatie": ["Skin Corr. 1A"],
      "h_zinnen": ["H314"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 1",
      "pgs15_ondergrens_kg": 250,
      "boven_ondergrens": false,
      "adr_niveau": "basis",
      "clp_niveau": null,
      "opmerkingen": "Mogelijk H315/H319 bij lage concentratie."
    },
    {
      "id": 5,
      "naam": "Calcium oxide",
      "naam_nl": "Calciumoxide",
      "cas": "1305-78-8",
      "adr_klasse": 8,
      "adr_verpakkingsgroep": "III",
      "adr_un": "UN 1910",
      "vorm": "vast",
      "hoeveelheid_liter": null,
      "hoeveelheid_kg": 10,
      "eenheid": "kg",
      "verpakking": "Canister",
      "clp_classificatie": ["Skin Corr. 1B", "STOT SE 3"],
      "h_zinnen": ["H314", "H335"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 2",
      "pgs15_ondergrens_kg": 250,
      "boven_ondergrens": false,
      "adr_niveau": "basis",
      "clp_niveau": null,
      "opmerkingen": "ADR 8 VG III aangenomen (in registratie als N/A). Reageert exotherm met water. Mogelijk ADR 4.3."
    },
    {
      "id": 6,
      "naam": "Vanadium(V) oxide",
      "naam_nl": "Vanadium(V) oxide (V₂O₅)",
      "cas": "1314-62-1",
      "adr_klasse": 6.1,
      "adr_verpakkingsgroep": "II",
      "adr_un": "UN 2862",
      "vorm": "vast_poeder",
      "hoeveelheid_liter": null,
      "hoeveelheid_kg": null,
      "eenheid": "kg",
      "verpakking": "TBV",
      "clp_classificatie": ["Carc. 1B", "Repr. 2", "Acute Tox. 2", "Acute Tox. 4", "Eye Dam. 1", "STOT SE 1", "STOT RE 1"],
      "h_zinnen": ["H350i", "H361fd", "H330", "H302", "H312", "H318", "H335", "H372"],
      "cmr_status": true,
      "cmr_categorie": "1B",
      "acute_tox_categorie": 2,
      "acute_tox_h_zinnen": ["H330"],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak 3",
      "pgs15_ondergrens_kg_adr": 50,
      "pgs15_ondergrens_kg_clp": 1,
      "pgs15_ondergrens_kg_cmr": 25,
      "boven_ondergrens": true,
      "adr_niveau": "C",
      "clp_niveau": "C",
      "opmerkingen": "KRITIEKE STOF — bepaalt C-niveau. Dodelijk bij inademing, kankerverwekkend. Hoeveelheid TBV door Phoenix Metals. Seveso H2 lagedrempel 50 ton."
    },
    {
      "id": 7,
      "naam": "Aluminum sulfate octadecahydrate",
      "naam_nl": "Aluminiumsulfaat octadecahydraat",
      "cas": "7784-31-8",
      "adr_klasse": null,
      "adr_verpakkingsgroep": null,
      "adr_un": null,
      "vorm": "vast",
      "hoeveelheid_liter": null,
      "hoeveelheid_kg": 5,
      "eenheid": "kg",
      "verpakking": "Canister",
      "clp_classificatie": ["Eye Irrit. 2"],
      "h_zinnen": ["H319"],
      "cmr_status": false,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "Vak C",
      "pgs15_ondergrens_kg": null,
      "boven_ondergrens": false,
      "adr_niveau": null,
      "clp_niveau": null,
      "opmerkingen": "Geen ADR, geen CMR, geen Acute Tox. → buiten PGS 15 toepassingsgebied."
    },
    {
      "id": 8,
      "naam": "Vanadium(IV) sulfate solution",
      "naam_nl": "Vanadium(IV) sulfaat oplossing",
      "cas": null,
      "adr_klasse": null,
      "adr_verpakkingsgroep": null,
      "adr_un": null,
      "vorm": "vloeistof",
      "hoeveelheid_liter": null,
      "hoeveelheid_kg": null,
      "eenheid": "L",
      "verpakking": "TBV",
      "clp_classificatie": ["TBV"],
      "h_zinnen": ["TBV"],
      "cmr_status": null,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "TBV",
      "pgs15_ondergrens_kg": null,
      "boven_ondergrens": null,
      "adr_niveau": null,
      "clp_niveau": null,
      "opmerkingen": "Tussenproduct. Classificatie TBV via SDS. Mogelijk ADR 6.1, mogelijke Acute Tox."
    },
    {
      "id": 9,
      "naam": "Vanadium electrolyte (V³·⁵⁺)",
      "naam_nl": "Vanadium elektrolyt (V³·⁵⁺)",
      "cas": null,
      "adr_klasse": null,
      "adr_verpakkingsgroep": null,
      "adr_un": null,
      "vorm": "vloeistof",
      "hoeveelheid_liter": null,
      "hoeveelheid_kg": null,
      "eenheid": "L",
      "verpakking": "TBV",
      "clp_classificatie": ["TBV"],
      "h_zinnen": ["TBV"],
      "cmr_status": null,
      "cmr_categorie": null,
      "acute_tox_categorie": null,
      "acute_tox_h_zinnen": [],
      "svhc_zzs": false,
      "onbrandbaar": true,
      "opslag_vak": "TBV",
      "pgs15_ondergrens_kg": null,
      "boven_ondergrens": null,
      "adr_niveau": null,
      "clp_niveau": null,
      "opmerkingen": "Finaal mengsel. Classificatie TBV via SDS. Mogelijk ADR 6.1."
    }
  ],
  "aggregatie": {
    "adr8": {
      "klasse": "ADR 8",
      "stoffen": [1, 2, 3, 4, 5],
      "totaal_kg": 410,
      "onbrandbaar": true,
      "niveau": "basis",
      "reden": "ADR 8 VG II+III, onbrandbaar, geen Acute Tox. → basisveiligheidsniveau (Tabel 6 voetnoot c)"
    },
    "adr61": {
      "klasse": "ADR 6.1",
      "stoffen": [6],
      "totaal_kg": "TBV",
      "onbrandbaar": true,
      "niveau": "C",
      "reden": "ADR 6.1 VG II, <10 ton → C-niveau (Wbdbo 60 min)"
    },
    "clp_acute_tox_2": {
      "categorie": "CLP Acute Tox. Cat. 2",
      "stoffen": [6],
      "h_zinnen": ["H330"],
      "ondergrens_kg": 1,
      "niveau": "C",
      "reden": "Acute Tox. 2 (H330), <10 ton → C-niveau"
    },
    "cmr_1b": {
      "categorie": "CMR Cat. 1B",
      "stoffen": [6],
      "h_zinnen": ["H350i"],
      "ondergrens_kg": 25,
      "niveau": "via_adr",
      "reden": "V₂O₅ heeft ADR-classificatie → via ADR 6.1 route. Aanvullende arbo-maatregelen verplicht."
    }
  },
  "niveaubepaling": {
    "bepaald_niveau": "C",
    "wbdbo_minuten": 60,
    "bepalende_stof": "Vanadium(V) oxide (V₂O₅)",
    "bepalende_routes": ["ADR 6.1 VG II", "CLP Acute Tox. 2 (H330)"],
    "schaalniveaus": {
      "basis": "Geen V₂O₅ opslag",
      "C": "1 kg – 10.000 kg V₂O₅",
      "A": ">10.000 kg V₂O₅ (automatische blussing verplicht)"
    }
  },
  "scheiding": [
    {
      "stof_1": "H₂SO₄ (zuren)",
      "stof_2": "NaOH (basen)",
      "risico": "Zuur-base reactie, hitteontwikkeling",
      "methode": "Min. 2,4 m afstand of ≥30 min Wbdbo wand",
      "geimplementeerd": false
    },
    {
      "stof_1": "V₂O₅ (ADR 6.1)",
      "stof_2": "ADR 8 stoffen",
      "risico": "Onverenigbaar",
      "methode": "Min. 2,4 m afstand of constructieve scheiding",
      "geimplementeerd": false
    }
  ],
  "openstaande_punten": [
    {"id": "OP-01", "prioriteit": "kritiek", "omschrijving": "Bevestig maximale opslaghoeveelheid V₂O₅"},
    {"id": "OP-02", "prioriteit": "kritiek", "omschrijving": "Lever complete stoffenlijst"},
    {"id": "OP-03", "prioriteit": "kritiek", "omschrijving": "Specificeer maximale voorraden NaOH/H₂SO₄"},
    {"id": "OP-04", "prioriteit": "belangrijk", "omschrijving": "Lever SDS vanadium(IV) sulfaat"},
    {"id": "OP-05", "prioriteit": "belangrijk", "omschrijving": "Lever SDS vanadium elektrolyt"},
    {"id": "OP-06", "prioriteit": "belangrijk", "omschrijving": "Inventariseer brandstoffen/smeermiddelen"}
  ]
}